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Biogeosciences Discuss., 7, 165-202, 2010
www.biogeosciences-discuss.net/7/165/2010/
doi:10.5194/bgd-7-165-2010
© Author(s) 2010. This work is distributed
under the Creative Commons Attribution 3.0 License.


Trends of anthropogenic CO2 storage in North Atlantic water masses

F. F. Pérez1, M. Vázquez-Rodríguez1, H. Mercier2, A. Velo1, P. Lherminier2, and A. F. Ríos1
1Instituto de Investigaciones Marinas, CSIC, Eduardo Cabello 6, 36208 Vigo, Spain
2Laboratoire de Physique des Océans, CNRS Ifremer IRD UBO, IFREMER Centre de Brest, B.P. 70 29280 Plouzané, France

Abstract. A high-quality inorganic carbon system database spanning over three decades (1981–2006) and comprising 13 cruises has allowed applying the φCT° method and coming up with accurate estimates of the anthropogenic CO2 (Cant) stored in the main water masses of the North Atlantic. In the studied region, strong convective processes convey surface properties, like Cant, into deeper ocean layers and confer this region an added oceanographic interest from the point of view of air-sea CO2 exchanges. Commonly, a tendency for decreasing Cant storage rates towards the deep layers has been observed. In the Iberian Basin, the deep waters (North Atlantic Deep Water) have low Cant values and negligible Cant storage rates, while the North Atlantic Central Water in the upper layers shows the largest Cant concentrations and capacity to increase its storage on a yearly basis (1.13±0.14 μmol kg−1 yr−1). This unmatched Cant storage capacity of the warm upper limb of the Meridional Overturning Circulation weakens towards the Irminger basin (0.68±0.06 μmol kg−1 yr−1) due to the lowering of the buffering capacity. The mid and deep waters in the Irminger Sea show rather homogeneous Cant storage rates (between 0.33 and 0.45 μmol kg−1 yr−1), whereas in the Iceland basin these layers seem to have been less affected by Cant. The Cant storage rates in the study region during the 1991–1997 high NAO (North Atlantic Oscillation) phase are ~48% higher than during the 1997–2006 low NAO phase that followed. This result suggests that a net decrease in the strength of the North Atlantic sink of atmospheric CO2has taken place during the present decade. The changes in deep-water ventilation together with a detrimental renewal of the main water masses are likely the main driving processes causing this weakening of the North Atlantic CO2sink.

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Citation: Pérez, F. F., Vázquez-Rodríguez, M., Mercier, H., Velo, A., Lherminier, P., and Ríos, A. F.: Trends of anthropogenic CO2 storage in North Atlantic water masses, Biogeosciences Discuss., 7, 165-202, doi:10.5194/bgd-7-165-2010, 2010.   Bibtex   EndNote   Reference Manager    XML